65.Gupta, R.; Kumar, A.; Mani, G. Dipyrromethane–Diphosphines: Nickel and Palladium Complexes as Catalysts for the Selective Hydroboration of CO₂ to Methoxyborane under Mild Conditions with Mechanistic Study. RSC Adv. 2026, 16, 45943–45953. DOI: 10.1039/d6ra04348h.

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64.Mondal, P.; Dutta, P.; Mani, G. Molybdenum(0)-Catalyzed Tandem Cyclization Reactions of Aminoalkynes with Diketones for Multiply Substituted Azaheterocycles. J. Org. Chem. 2026, 91, 11373–11384. DOI: 10.1021/acs.joc.6c01148

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63. Kumar, A.; Gupta, R.; Mani, G. The Hydroboration of CO2 with 9-BBN to Methoxyborane Catalyzed by Pincer Carbene Palladium(II) and Nickel(II) Thiolates with High Turnover Numbers. Organometallics, 2026, 45, 410–423. doi.org/10.1021/acs.organomet.5c00354 

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62. Mondal, M.; Mani, G. Synthesis and Structural Characterizations of Self-Assembled Silver(I) Complexes of the Pyrazole Ligands: Effect of anion and VT NMR Study. Polyhedron, 2026, 284, 117910. doi.org/10.1016/j.poly.2025.117910.

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61. Dutta, P.; Mondal, P.; Khatua, K.; Mani, G. The Tandem Reaction of Aminoalkynes Catalyzed by Copper Salts for Azaheterocycles: Product Selectivity by Temperature and X-ray Structure of an Iminium Ion. J. Org. Chem. 2025, 90, 11245–11256; 10.1021/acs.joc.5c01181.

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60. Kumar, A.; Gupta, R.; Mani, G. The DMSO-Catalyzed CO2 Reduction with 9-BBN as a Source for the Selective N-Formylation, Room Temperature N-Methylation of Amines, N-Hydroxymethylation of Heterocycles, and C–N Couplings. J. Org. Chem. 2025, 90, 10316–10331; https://pubs.acs.org/doi/full/10.1021/acs.joc.5c00965.

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59. Mondal, P.; Dutta, P.; Mani, G. Mo(0) carbonyl complexes bearing the bis(3,5-dimethylpyrazole) ligand: Catalysis of the regioselective [2+2+2] cycloaddition of terminal alkynes to synthesize 1,3,5-isomer. Dalton Trans., 2025, 54, 2654-2663. 10.1039/D4DT02725F

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58. Kumar, A.; Gupta, R.; Subramaniyan, V.; Mani, G. DMSO-catalyzed CO2 reduction with 9-BBN: selective formation of either formoxy- or methoxyborane under mild conditions and C-methylenation of indoles. Catal. Sci. Technol, 2025, 15, 678-688. 10.1039/D4CY01327A

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57. Debnath, S.; Giri, S.; Mani, G. Selective synthesis of the missing tiara-like Ni10, Ni5 and Ni6 thiolates by the C-S bond cleavage of bis(thioether) molecules with DFT study. Dalton Trans., 2024, 53, 14875-14886. DOI: 10.1039/D4DT02047B. 

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56. Mondal, M.; Mani, G. Copper(I) Complexes Bearing the Pyrrole-Bridged S,N and N-Donor Ligands as Catalysts for the Tandem Hydroamination-Alkynylation: Effect of Anions on Product Formation, Dalton Trans., 2024, 53, 13996 - 14010;  DOI: 10.1039/D4DT01937G 

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55. Gupta, R.; Kumar, A.; and Mani, G. Dipyrromethane–diphosphine:the effect of meso substituents on the formation of nickel complexes and on their performance in the transfer hydrogenation of ketones, Dalton Trans. 2023, 52, 18332-18341.

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54. Kumar, A.; Gupta, R.; and Mani, G. PCP Pincer Carbene Nickel(II) Chloride, Hydride, and Thiolate Complexes: Hydrosilylation of Aldehyde, Ketone, and Nitroarene by the Thiolate Complex, Organometallics 2023, 42, 732−744.

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53. Panigrahi, D.; Mondal, M.; Mani, G. Four- and five-coordinate nickel(II) complexes bearing new diphosphine-phosphonite and triphosphine-phosphite ligands: catalysts for N-alkylation of amines. RSC Adv., 2022, 12, 4510-4520.

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52. Jha, V. K.; Das, S.; Subramaniyan, V.; Guchhait, T.; Dakua, K. K.; Mishra, S.; Mani, G. Synthesis, structural characterization, and bonding analysis of two-coordinate copper(I) and silver(I) complexes of the pyrrole-based bis(phosphinimine): new metal-pyrrole ring p interactions, Dalton Trans., 2021, 50, 8036-8044.

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51. Panigrahi, D.; Subramaniyan. V.; Mani, G. Synthesis and Structural Characterizations of Pd(II) Complexes Bearing the New Hexahydropyrimidine and Tetrahydropyrimidinium Based Bis(pyrazole) Ligands with DFT Studies, J. Mol. Struc., 2021, 1231, 129949.

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50. Kumar, R.; Guchhait, T.; Subramaniyan, V.; Schulzke, C.; Mani, G. Versatility of the bis(iminopyrrolylmethyl)amine ligand: tautomerism, protonation, helical chirality, and secondary coordination sphere with halogen bonds in the formation of copper(II) and nickel(II) complexes

Dalton Trans., 2020, 49, 13840, DOI: 10.1039/D0DT02964E.

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49. Subramaniyan, V.; Kumar, A.; Mani, G. New Spiro-borane and Spiro-borate Derived from Dipyrromethane and their H/D Exchange Properties, Polyhedron, 2020, 186, 114612. https://doi.org/10.1016/j.poly.2020.114612.

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48. Das, S.; Subramaniyan, V.; Mondal, M.; Mani, G. Synthesis, X‐Ray Structures, and Fluxional Properties of Symmetrical, Asymmetrical Binuclear and Cubane Type Copper(I) Complexes Bearing the Pyrrole‐Based P, N‐Hetero Donor Ligand, ChemistrySelect, 2020, 5, 5006-5012. https://doi.org/10.1002/slct.202001312

47. Jana, D.; Guchhait, T.; Subramaniyan, V.; Kumar, A. Mani, G. Mannich Reaction of Pyrrole and Dimethylpyrrole with Monoamines and Diamines, Tetrahedron Lett., 2019, 60, 151247.  doi.org/10.1016/j.tetlet.2019.151247

46. Kumar, R.; Guchhait, T.; Subramaniyan, V.; Mani, G. Mixed Ligand Cu(II) Complexes: Square Pyramidal vs Trigonal Bipyramidal with the Pyrrole-based Dipodal Ligand Having Hydrogen Bond Acceptors, J. Mol. Struct., 2019, 1195, 1-9.

45. Subramaniyan, V.; Kumar, A.; Govindaraj, A.; Mani, G. Crystal Structure and DFT Analyses of a Penta-coordinated PCP Pincer Nickel(II) Complex. Acta Cryst. 2019, C75, 734–739.

44. Das, S.; Subramaniyan, V.; Mani, G. Nickel(II) and Palladium(II) Complexes Bearing an Unsymmetrical Pyrrole-based PNN Pincer and their Norbornene Polymerization Behaviors Versus the Symmetrical NNN and PNP Pincers, Inorg. Chem., 2019, 58, 3444–3456.

43. Mani, G.; Subramaniyan, V. Homoleptic and Heteroleptic Copper(I) Complexes Bearing Diimine-Diphosphine Ligands, Chapter 8 in ‘Copper(I) Chemistry of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles’ Edited by Balakrishna, M. S., Elsevier Publications, 2019, 237-258.

42. Subramaniyan, V.; Dutta, B.; Govindaraj, A.; Mani, G. Facile Synthesis of Pd(II) and Ni(II) Pincer Carbene Complexes by the Double C-H Bond Activation of a New Hexahydropyrimidine-Based Bis(phosphine): Catalysis of C-N Couplings, Dalton Transactions, 2019, 48, 7203 - 7210 (invited article for the New Talent: Asia Pacific themed issue of Dalton Transactions)

41. Jana, O.; Mani, G. Enantiomers and Structural Isomers of Sodium and Palladium Complexes Bearing ortho-Bis(3,5-dimethylpyrazolylmethyl)phenolate: Fluxional Property and Highly Active Catalysts for Norbornene Polymerization. Inorg. Chem. 2018, 57, 7735-7747.

40. Kumar, S.; Jana, O.; Subramaniyan, V.; Mani, G. The ‘Reverse Transmetalation’ Reaction of the Pyrrole-Based PNP Pincer Ni(II) Complexes: X-ray Structures of Binuclear Silver(I) and Thiocyanate Nickel(II) Complexes. Inorg. Chim. Acta. 2018, 480, 113.

39. Subramaniyan, V.; Mani, G. Synthesis, Reactions, and Structures of Heterocycle-Tethered Boranes and Their Precursors, Organometallics, 2018, 37, 127−135.

38. Jana, O.; Mani, G. New types of Cu and Ag clusters supported by the pyrrole-based NNN-pincer type ligand, New J. Chem., 2017, 41, 9361-9370.

37. Jha,V. K.; Mani, G.; Davuluri, Y. R;. Anoop, A. The pyrrole ring η2-hapticity bridged binuclear tricarbonyl Mo(0) and W(0) complexes: catalysis of regioselective hydroamination reactions and DFT calculations, Dalton Trans., 2017, 46, 1840-1847.

36. Guchhait, T.; Mani, G.; Schulzke, C. Synthesis and structural characterization of anion complexes with azacalix[2]dipyrrolylmethane: effect of anion charge on the conformation of the macrocycle Dalton Trans. 2016, 45, 11781 - 11790.

35. Kumar, R.; Paul, T.; Jana, ).; Mani, G. Regioselective Mannich bases of pyrrole-2-carbaldehyde and binuclear copper(II) complexes of bis(iminopyrrolyl) ligand containing the piperazine ring Inorg. Chim. Acta. 2016, 445, 70-78.

34. Kumar, S.; Mani, G. Synthesis and structural characterization of chromium(III) complexes bearing 3,5-dimethylpyrazolate ligand Polyhedron, 2015, 99, 47-52.

33. Jana, D.; Das, S.; Mani, G. Self Assembled Macrobicycle and Tricycle Cages Containing Pyrrole Rings by Dynamic Covalent Chemistry Method. J. Incl.  Phenom.  Macrocycle. Chem. 2015, 82, 461-470.

32. Guchhait, T.; Barua, B.; Biswas, A.; Basak, B.; Mani, G. Synthesis and structural characterization of silver(I), copper(I) coordination polymers and a helicate palladium(II) complex of dipyrrolylmethane-based dipyrazole ligands: the effect of meso substituents on structural formation Dalton Trans., 2015, 44, 9091-9102.

31. Kumar, R.; Mani, G. Exhibition of the Brønsted acid–base character of a Schiff base in palladium(II) complex formation: lithium complexation, fluxional properties and catalysis of Suzuki reactions in water Dalton Trans., 2015, 44, 6896–6908.

30. Ghorai, D.; Mani, G. Unsubstituted quinoidal pyrrole and its reaction with oxygen, charge transfer and palladium(II) complexes via DDQ oxidation RSC Adv., 2014, 4, 45603-45611.

29. Ghorai, D.; Mani, G. Single-Step Substitution of all the α, β-Positions in Pyrrole: Choice of Binuclear versus Multinuclear Complex of the Novel Polydentate Ligand Inorg. Chem., 2014, 53, 4117–4129.

28. Kumar, S.; Mani, G.; Dutta, D.; Mishra, S. Structural Diversity of Copper(I) Complexes Formed by Pyrrole- and Dipyrrolylmethane-Based Diphosphine Ligands with Cu–X···HN Hydrogen Bonds Inorg. Chem. 2014, 53, 700–709.

27. Jana, D.; Mani, G.; Schulzke, C. Synthesis of Novel Polyazacryptands for Recognition of Tetrahedral Oxoanions and Their X-ray Structures Inorg. Chem. 2013, 52, 6427–6439.

26. Guchhait, T.; Jha, V. K.; Mani, G. The syn and anti isomers of the porphyrinogen-like precursor of calix[4]phyrin: isolation, X-ray structure, anion binding and fluoride-ion-mediated proton–deuterium exchange studies Org. Biomol. Chem., 2013, 11, 2818-2826.

25. Kumar, S.; Mani, G.; Mondal, S.; Chattaraj, P. K. Pyrrole-Based New Diphosphines: Pd and Ni Complexes Bearing the PNP Pincer Ligand Inorg. Chem., 2012, 51, 12527-12539.

24. Guchhait, T.; Mani, G.; Schulzke, C.; Anoop, A. A Tripyrrolylmethane-Based Macrobicyclic Triazacryptand: X-ray Structure, Size-Selective Anion Binding, and Fluoride-Ion-Mediated Proton–Deuterium Exchange Studies Inorg. Chem., 2012, 51, 11635–11644.

23. Kumar, R.; Guchhait, T.; Mani, G. Synthesis and X-ray Structures of Novel Macrocycles and Macrobicycles Containing N,N-Di(pyrrolylmethyl)-N-methylamine Moiety: Preliminary Anion Binding Study Inorg. Chem., 2012, 51, 9029–9038.

22. Ghorai, D.; Kumar, S.; Mani, G. Mononuclear, helical binuclear palladium and lithium complexes bearing a new pyrrole-based NNN-pincer ligand: fluxional property Dalton Trans., 2012, 41, 9503-9512.

21. Guchhait, T.; Mani, G. Dipyrrolylmethane-based Macrobicyclic Azacryptand: Synthesis, X-ray Structures, Conformational and Anion Binding Properties J. Org. Chem., 2011, 76, 10114-10121.

20. Ghorai, D.; Mani, G. Synthesis and structural characterization of Pd(II) complexes containing 2,6-bis[(dimethylamino)methyl]-4-methylphenolate ligand Inorg. Chim. Acta., 2011, 372, 412-416.

19. Mani, G.; Guchhait, T.; Kumar, R.; Kumar, S. Macrocyclic and Acyclic Molecules Synthesized from Dipyrrolylmethanes: Receptors for Anions, Org. Lett. 2010, 12, 3910–3213.

18. Mani, G.; Jana, D.; Kumar, R.; Ghorai, D. Azatripyrrolic and Azatetrapyrrolic Macrocycles from the Mannich Reaction of Pyrrole: Receptors for Anions, Org. Lett. 2010, 12, 3212–3215.

17. Ganesan, M,;  Freemantle, R. G.; Obare, S. O., Monodisperse Thioether- Stabilized Palladium Nanoparticles: Synthesis, Characterization, and Reactivity, Chem. Mater., 2007, 19, 3464-3471.

16. Ganesan, M.; Gabbai, F.P. Synthesis, structure and catalytic properties of [Cp*Cr(C6F5)(Bn)(THF)] toward ethylene in the presence of AlEt3 J. Organomet. Chem. 2005, 690, 5145-5149.

15. Ganesan, M, Krishnamurthy S. S, Nethaji M., Di- and tri-nuclear molybdenum–palladium complexes bearing strong π-acceptor “P–N–P” ligands, MeN{P(OR)2}2 (R = CH2CF3 or Ph). J. Organomet. Chem. 2005, 690, 1080-1091.

14. Ganesan, M.; Gabbai, F.P. [Cp*Cr(C6F5)(Me)(Py)] as a Living Chromium(III) Catalyst for the "Aufbaureaktion" Organometallics, 2004, 23, 4608-4613.

13. Ganesan, M.; Gabbaï, F.P. A neutral chromium(III) catalyst for the living “Aufbaureaktion”  Angew. Chem. Int. Ed. Engl. 2004, 43, 2263-2266.

12. Ganesan, M.; Fanwick, P.E.; Walton, R.A. The synthesis of the triply bonded tetramethyl complex Re2(CH3)4(m-dppm)2 and its reaction with CO to afford   Re2(m-CH2)2(CO)4(m-dppm)2. J. Organomet. Chem. 2003, 671, 166-171.

11. Ganesan, M.; Fanwick, P.E.; Walton, R.A. Reaction of the bis(iminophosphoranyl)methane ligand CH2(Ph2P=NsiMe3) with nickel(II) halides and the structural characterization of ligand fragmentation products, Inorg. Chim. Acta. 2003, 346, 181-186.

10. Ganesan, M.; Shih, K.Y.; Fanwick, P.E.; Walton, R.A. Complexation of the triply-bonded dirhenium(II) complex Re2Cl4(m-dppm)2 (dppm = Ph2PCH2PPh2) by up to three acetylene molecules, Inorg. Chem. 2003, 42, 1241-1247.

9. Ganesan, M.; Fanwick, P.E.; Walton, R.A. The synthesis and structural characterization of the m-sulfur dioxide complex Re2(m-SO2)(m-Cl)Cl4(m-dppm)2, Inorg. Chim. Acta. 2003, 343, 391-394.

8. Ganesan, M.; Fanwick P.E.; Walton R.A. A Novel Example of the Reductive Cyclization of a Diyne at a Re-Re Triple Bond: The Reaction of Re2Cl4(m-dppm)2 with 1,7-Octadiyne, Organometallics,  2003,  22,  870-872.

7. Ganesan, M.; Kapoor P.N.; Fanwick P.E.; Walton R.A. The first examples of triply bonded dirhenium(II) complexes that contain b-diketonate ligands, Inorg. Chem. Commun., 2002, 5, 1073-1077.

6. Ganesan, M.; Bérubé C.D.; Gambarotta S.; Yap G.P.A. Synthesis of Samarium and Ytterbium Complexes with 2,5-Dimethylpyrrole: The Effect of the Alkali Cation on the Bonding Mode of Divalent Lanthanide Centres, Organometallics, 2002, 21, 1707-1713.

5. Ganesan, M.; Lalonde M. P.; Gambarotta S.; Yap G.P.A. Isolation and Characterization of Linear Polymeric {[1,1-H10C6(a-C4H3N)2]2Sm[Na(THF)]2}n: A 30-Electron Species with a (h5-Cp)4Ln Type Structure,   Organometallics, 2001, 20, 2443-2445. 

4. Ganesan, M.; Gambarotta S.; Yap G.P.A. Highly Reactive Sm(II) Macrocyclic Clusters: Precursors to N2 Reduction, Angew. Chem. Int. Ed. 2001, 40, 766-769.

3. Dube T.; Ganesan, M.; Conoci S.; Gambarotta S.; Yap G.P.A. Tetrametallic Divalent Samarium Cluster Hydride and Dinitrogen Complexes, Organometallics, 2000, 18, 3716-3721.

2. Ganesan, M.; Krishnamurthy, S. S.; Nethaji, M.; Raghuraman, K. Phosphorus, Sulfur and Silicon, 1999, 147, 355-355.

1. Ganesan, M.; Krishnamurthy, S.S.; Nethaji, M. Reductive carbonylation route to Co(0) and Co(I) carbonyl complexes containing bridging, chelating and cleaved diphosphazanes. Structures of [Co(CO){P(OR)2(NHMe)}2{P(O)(OR)2}{P(H)(OR)2}] (R = CH2CF3, R = CH2CH3), [Co2(CO)2{m-MeN{P(OR)2}2}3] (R = CH2CF3), and [Co(CO){h2-MeN{P(OR)2}2}2][CoCl3(OC4H8)] (R = Ph) J. Organomet. Chem. 1998, 570, 247-254.